Scientists Created a Plastic That’s Infinitely Recyclable

What if the answer to our massive plastic
waste problem was a new material that could take any shape, any color, be used in any
way and instead of having to throw it away at the end of its lifetime, we could just
recycle it forever? Well… that material just might be here in
the form of a brand new kind of plastic. Recycling plastic is actually trickier than
it sounds. First of all, plastic is super diverse, so
you can’t use the same recycling process on all the different plastic things we make. Looking at these horrific displays of plastics
polluting the environment, whether that was in our oceans or on land and in landfills. And it was pretty clear that plastics needed
a redo in terms of how we design them, specifically addressing the eventuality that their end
of life needed to be revisited a little bit. The “end life” is why plastic products
have to be separated into different streams to be recycled in different ways. The polymers will respond different to heat
during the recycling process. Hence the various numbers you see on the bottom
of the containers—and even then, not all plastics with the same number can be recycled
together. Most commercial plastics contain lots of extras,
or additives, like dyes and ingredients to make them stronger or more heat-resistant. These additives are very difficult to remove
from the plastic, making it hard to recycle just the plastic. Or the monomer building blocks, and the presence
of the additives can also make the resulting recycled plastic product unreliable and unpredictable. So, all of those additives end up becoming
associated with the plastic. That heterogeneity essentially makes it very,
very, very difficult to think about what to do with the plastic outside of grinding it
up into little pieces and trying to pelletize it with a bunch of other different plastics
that all have their own additives. But luckily, new innovations are leading to
plastics that could be infinitely recycled. The team at Lawrence Berkeley National Lab
has turned to a new kind of plastic called poly(diketoenamine) or PDK for short. PDKs are an interesting type of plastic that
differ from conventional plastics in that we
completely replaced the static covalent bonds that typically comprise… that make up the
polymer backbone and we replaced them with dynamic covalent bonds that allow you to do
a number of new things. Picture the bonds of a polymer in a traditional
plastic like a metal chain. To break down the plastic, you have to break
the links of the chain and then spend time and energy trying to re-form them, with the
addition of a lot of glue and maybe even some new metal. With a material like PDK, the links between
atoms in the polymer chain are actually reversible. Because they use dynamic bonds between monomers
called diketoenamines, which is a triketone and amine stuck together. You can just open ‘em up by dunking them
in an acid bath and separate them from their additives, ready to use the plastic again. And the end result is the fluffy powder that’s
actually the exact same plastic from the beginning of the process, it didn’t lose any of its
integrity in the recycling process! And the acid isn’t far from what researchers
already use in the lab. Honestly anything below a pH 1 could work,
but the final call was sulfuric acid and for a couple different reasons. Sulfuric acid as a result, because it’s
a byproduct of petroleum refining, is very, very inexpensive. So, acid is used to depolymerize PDKs and
in the course of depolymerizing PDKs and once you go through the full cycle of recycling
both the triketones and the amine monomers, you generate salty water. And this salty water can be recovered and
purified by reverse osmosis facilities. These types of facilities would be able to
also recover the water and recover the commodity value of the chemicals embodied by the salt
in the water as well. And so, I think that that sets up a landscape
for being able to do efficient resource recovery even while you’re doing PDK plastic, chemical
circularity. The hope is that PDK could pave the way for
plastic products that are infinitely recyclable in the same way that glass and metal are. While this material is still in its early
stages, the researchers are looking at how we could incorporate PDK into existing manufacturing
processes, experimenting with how it could be used in textiles, shoes, and food packaging. And I think what we need to do is figure out
of the sustainability challenges that we have in specific markets, where are those best
solved by this particular plastic? And in solving that, do we also identify what
might be needed to advance the next design that is also circular. Which is essential, because in 2015, the U.S.
actually only recycled 9% of its generated plastics. The rest goes to landfills, is incinerated,
or apparently makes its way to the ocean. Over 13 million metric tonnes of plastic end
up in the ocean each year, so unless we want to lose our oceans and be buried under mountains
of trash à la Wall-E, something’s gotta give. This new material holds great promise for
modernizing our recycling world and making it more efficient, hopefully pushing toward
a world where plastic products are not only much more recyclable, but don’t end up in
a landfill or our oceans at all. If you’re interested in how plastics are
probably getting into your body through the food you’re eating, check this other video
here. Make sure to subscribe to Seeker to stay up-to-date
with world-changing materials science discoveries, and thanks for watching.

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